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Sustaining energy systems using metal oxide composites as photocatalyst  2021, 2 (1): 6-15  DOI 10.37357/1068/jser.2.1.02


Mir Sayed Shah Danish 
Strategic Research Project Center, University of the Ryukyus, Okinawa 903-0213, Japan

Tomonobu Senjyu 
Department of Electrical and Electronics Engineering, Faculty of Engineering, University of the Ryukyus, Okinawa 903-0213, Japan

Abdul Matin Ibrahimi 
Department of Electrical and Electronics Engineering, Faculty of Engineering, University of the Ryukyus, Okinawa 903-0213, Japan

Arnab Bhattacharya 
Department of Academic Affairs, Research and Education Promotion Association (REPA), Okinawa 900-0015, Japan

Zahra Nazari 
Department of Computer Science, Kabul Polytechnic University, Kabul 1006, Afghanistan

Sayed Mir Shah Danish 
Department of Electrical Engineering, Technical Teachers Training Academy (TTTA), Chihl Sutton, Kabul, Afghanistan

Mikaeel Ahmadi 
Department of Electrical and Electronics Engineering, Faculty of Engineering, University of the Ryukyus, Okinawa 903-0213, Japan

Among the various types of metal organic frameworks (MOFs), the metal-oxide-based ones fulfill all the essential criteria such as strong bonding, organic linking units, and highly crystalline nature, properties required to be effective photocatalysts to serve environmental remediation. Moreover, the even spread of active sites and semiconductor properties make the MOFs ideal for absorbing irradiation from UV as well as visible light sources. Metal oxide composites with carbon based materials, especially, show high photocatalytic activity toward the degradation of organic dyes. Considering the relatively low cost of metal oxide semiconductors compared to pure metallic nanoparticles, metal oxide composites can provide a great alternative as photocatalysts especially considering the adjustable bandgaps and synergistic effects. Therefore, the metal oxide application as the photocatalysts in industry and technology in terms of techno-economic advantage is attracted. In this study, energy sustainability and solving carbon-related issues through metal oxide-based materials are discussed. This study aims to review metal oxide composites including metal oxide-MOFs and metal oxide-carbon material compositions as photocatalysts, application, merits in environmental and energy systems performances, and its contribution as an influential factor for sustainable development.
 
  1. Emam HE, Ahmed HB, Gomaa E, Helal MH, Abdelhameed RM (2019) “Doping of silver vanadate and silver tungstate nanoparticles for enhancement the photocatalytic activity of MIL-125-NH2 in dye degradation” Journal of Photochemistry and Photobiology A: Chemistry (vol. 383, pp. 111986) https://doi.org/10.1016/j.jphotochem.2019.111986
  2. Zhang C, Ai L, Jiang J (2015) “Graphene hybridized photoactive iron terephthalate with enhanced photocatalytic activity for the degradation of rhodamine b under visible light” Ind Eng Chem Res (vol. 54, no. 1, pp. 153–163) https://doi.org/10.1021/ie504111y
  3. Rad M, Dehghanpour S (2016) “ZnO as an efficient nucleating agent and morphology template for rapid, facile and scalable synthesis of MOF-46 and ZnO@MOF-46 with selective sensing properties and enhanced photocatal ytic ability” RSC Adv (vol. 6, no. 66, pp. 61784–61793) https://doi.org/10.1039/C6RA12410K
  4. Wang X, Liu J, Leong S, Lin X, Wei J, et al. (2016) “Rapid construction of ZnO@ZIF-8 heterostructures with size-selective photocatalysis properties” ACS Appl Mater Interfaces (vol. 8, no. 14, pp. 9080–9087) https://doi.org/10.1021/acsami.6b00028
  5. Mahmoodi NM, Taghizadeh A, Taghizadeh M, Abdi J (2019) “In situ deposition of Ag/AgCl on the surface of magnetic metal-organic framework nanocomposite and its application for the visible-light photocatalytic degradation of Rhodamine dye” Journal of Hazardous Materials (vol. 378, pp. 120741) https://doi.org/10.1016/j.jhazmat.2019.06.018
  6. Jiang D, Xu P, Wang H, Zeng G, Huang D, et al. (2018) “Strategies to improve metal organic frameworks photocatalyst’s performance for degradation of organic pollutants” Coordination Chemistry Reviews (vol. 376, pp. 449–466) https://doi.org/10.1016/j.ccr.2018.08.005
  7. Xie M-H, Shao R, Xi X-G, Hou G-H, Guan R-F, et al. (2017) “Metal–organic framework photosensitized TiO2 co-catalyst: A facile strategy to achieve a high efficiency photocatalytic system” Chemistry – A European Journal (vol. 23, no. 16, pp. 3931–3937) https://doi.org/10.1002/chem.201605282
  8. Li H, Li Q, He Y, Zhang N, Xu Z, et al. (2018) “Facile fabrication of magnetic metal-organic framework composites for the highly selective removal of cationic dyes” Materials (vol. 11, no. 5, pp. 744) https://doi.org/10.3390/ma11050744
  9. Zhao X, Liu S, Tang Z, Niu H, Cai Y, et al. (2015) “Synthesis of magnetic metal-organic framework (MOF) for efficient removal of organic dyes from water” Sci Rep (vol. 5, no. 1, pp. 11849) https://doi.org/10.1038/srep11849
  10. Zhang M, Qiao R, Hu J (2020) “Engineering Metal–Organic Frameworks (MOFs) for Controlled Delivery of Physiological Gaseous Transmitters” Nanomaterials (vol. 10, no. 6, pp. 1134) https://doi.org/10.3390/nano10061134
  11. Li Y, Zhou X, Dong L, Lai Y, Li S, et al. (2019) “Magnetic metal-organic frameworks nanocomposites for negligible-depletion solid-phase extraction of freely dissolved polyaromatic hydrocarbons” Environmental Pollution (vol. 252, pp. 1574–1581) https://doi.org/10.1016/j.envpol.2019.04.137
  12. Torretta V, Katsoyiannis IA, Viotti P, Rada EC (2018) “Critical review of the effects of glyphosate exposure to the environment and humans through the food supply chain” Sustainability (vol. 10, no. 4, pp. 950) https://doi.org/10.3390/su10040950
  13. Danish MSS, Bhattacharya A, Stepanova D, Mikhaylov A, Grilli ML, et al. (2020) “A systematic review of metal oxide applications for energy and environmental sustainability” Metals (vol. 10, no. 12, pp. 1604) https://doi.org/10.3390/met10121604
  14. Danish MSS, Estrella LL, Alemaida IMA, Lisin A, Moiseev N, et al. (2021) “Photocatalytic applications of metal oxides for sustainable environmental remediation” Metals (vol. 11, no. 1, pp. 80) https://doi.org/10.3390/met11010080
  15. He X, Nguyen V, Jiang Z, Wang D, Zhu Z, et al. (2018) “Highly-oriented one-dimensional MOF-semiconductor nanoarrays for efficient photodegradation of antibiotics” Catal Sci Technol (vol. 8, no. 8, pp. 2117–2123) https://doi.org/10.1039/C8CY00229K
  16. Moradi SE, Haji Shabani AM, Dadfarnia S, Emami S (2016) “Effective removal of ciprofloxacin from aqueous solutions using magnetic metal–organic framework sorbents: mechanisms, isotherms and kinetics” J IRAN CHEM SOC (vol. 13, no. 9, pp. 1617–1627) https://doi.org/10.1007/s13738-016-0878-y
  17. Huo J-B, Xu L, Chen X, Zhang Y, Yang J-CE, et al. (2019) “Direct epitaxial synthesis of magnetic Fe3O4@UiO-66 composite for efficient removal of arsenate from water” Microporous and Mesoporous Materials (vol. 276, pp. 68–75) https://doi.org/10.1016/j.micromeso.2018.09.017
  18. Ma Y, Xu G, Wei F, Cen Y, Xu X, et al. (2018) “One-pot synthesis of a magnetic, ratiometric fluorescent nanoprobe by encapsulating Fe3O4 magnetic nanoparticles and dual-emissive rhodamine b modified carbon dots in metal–organic framework for enhanced HClO sensing” ACS Appl Mater Interfaces (vol. 10, no. 24, pp. 20801–20805) https://doi.org/10.1021/acsami.8b05643
  19. Gu C, Xiong S, Zhong Z, Wang Y, Xing W (2017) “A promising carbon fiber-based photocatalyst with hierarchical structure for dye degradation” RSC Adv (vol. 7, no. 36, pp. 22234–22242) https://doi.org/10.1039/C7RA02583A
  20. Nekouei S, Nekouei F, Kargarzadeh H (2018) “Synthesis of ZnO photocatalyst modified with activated carbon for a perfect degradation of ciprofloxacin and its secondary pollutants” Applied Organometallic Chemistry (vol. 32, no. 3, pp. e4198) https://doi.org/10.1002/aoc.4198
  21. Atchudan R, Edison TNJI, Perumal S, Karthik N, Karthikeyan D, et al. (2018) “Concurrent synthesis of nitrogen-doped carbon dots for cell imaging and ZnO@nitrogen-doped carbon sheets for photocatalytic degradation of methylene blue” Journal of Photochemistry and Photobiology A: Chemistry (vol. 350, pp. 75–85) https://doi.org/10.1016/j.jphotochem.2017.09.038
  22. Wang F, Zhou Y, Pan X, Lu B, Huang J, et al. (2018) “Enhanced photocatalytic properties of ZnO nanorods by electrostatic self-assembly with reduced graphene oxide” Phys Chem Chem Phys (vol. 20, no. 10, pp. 6959–6969) https://doi.org/10.1039/C7CP06909J
  23. Jo W-K, Kumar S, Isaacs MarkA, Lee AF, Karthikeyan S (2017) “Cobalt promoted TiO2/GO for the photocatalytic degradation of oxytetracycline and Congo Red” Applied Catalysis B: Environmental (vol. 201, pp. 159–168) https://doi.org/10.1016/j.apcatb.2016.08.022
  24. Ahmed B, Ojha AK, Singh A, Hirsch F, Fischer I, et al. (2018) “Well-controlled in-situ growth of 2D WO3 rectangular sheets on reduced graphene oxide with strong photocatalytic and antibacterial properties” Journal of Hazardous Materials (vol. 347, pp. 266–278) https://doi.org/10.1016/j.jhazmat.2017.12.069
  25. Gan L, Xu L, Shang S, Zhou X, Meng L (2016) “Visible light induced methylene blue dye degradation photo-catalyzed by WO3/graphene nanocomposites and the mechanism” Ceramics International (vol. 42, no. 14, pp. 15235–15241) https://doi.org/10.1016/j.ceramint.2016.06.160
  26. Taha AA, Li F (2014) “Porous WO3–carbon nanofibers: high-performance and recyclable visible light photocatalysis” Catal Sci Technol (vol. 4, no. 10, pp. 3601–3605) https://doi.org/10.1039/C4CY00777H
  27. Song B, Wang T, Sun H, Shao Q, Zhao J, et al. (2017) “Two-step hydrothermally synthesized carbon nanodots/WO3 photocatalysts with enhanced photocatalytic performance” Dalton Trans (vol. 46, no. 45, pp. 15769–15777) https://doi.org/10.1039/C7DT03003G
  28. Jeevitha G, Abhinayaa R, Mangalaraj D, Ponpandian N (2018) “Tungsten oxide-graphene oxide (WO3-GO) nanocomposite as an efficient photocatalyst, antibacterial and anticancer agent” Journal of Physics and Chemistry of Solids (vol. 116, pp. 137–147) https://doi.org/10.1016/j.jpcs.2018.01.021
  29. Lee C-G, Javed H, Zhang D, Kim J-H, Westerhoff P, et al. (2018) “Porous electrospun fibers embedding TiO2 for adsorption and photocatalytic degradation of water pollutants” Environ Sci Technol (vol. 52, no. 7, pp. 4285–4293) https://doi.org/10.1021/acs.est.7b06508
  30. Gong Q, Liu Y, Dang Z (2019) “Core-shell structured Fe3O4@GO@MIL-100(Fe) magnetic nanoparticles as heterogeneous photo-Fenton catalyst for 2,4-dichlorophenol degradation under visible light” J Hazard Mater (vol. 371, pp. 677–686) https://doi.org/10.1016/j.jhazmat.2019.03.019
  31. Liu G, Li L, Xu D, Huang X, Xu X, et al. (2017) “Metal–organic framework preparation using magnetic graphene oxide–β-cyclodextrin for neonicotinoid pesticide adsorption and removal” Carbohydrate Polymers (vol. 175, pp. 584–591) https://doi.org/10.1016/j.carbpol.2017.06.074
  32. He R, Zhou J, Fu H, Zhang S, Jiang C (2018) “Room-temperature in situ fabrication of Bi2O3/g-C3N4 direct Z-scheme photocatalyst with enhanced photocatalytic activity” Applied Surface Science (vol. 430, pp. 273–282) https://doi.org/10.1016/j.apsusc.2017.07.191
  33. Wu Y, Wang H, Tu W, Liu Y, Tan YZ, et al. (2018) “Quasi-polymeric construction of stable perovskite-type LaFeO3/g-C3N4 heterostructured photocatalyst for improved Z-scheme photocatalytic activity via solid p-n heterojunction interfacial effect” Journal of Hazardous Materials (vol. 347, pp. 412–422) https://doi.org/10.1016/j.jhazmat.2018.01.025
  34. Jain M, Yadav M, Kohout T, Lahtinen M, Garg VK, et al. (2018) “Development of iron oxide/activated carbon nanoparticle composite for the removal of Cr(VI), Cu(II) and Cd(II) ions from aqueous solution” Water Resources and Industry (vol. 20, pp. 54–74) https://doi.org/10.1016/j.wri.2018.10.001
  35. Guo X, Liu Q, Liu J, Zhang H, Yu J, et al. (2019) “Magnetic metal-organic frameworks/carbon dots as a multifunctional platform for detection and removal of uranium” Applied Surface Science (vol. 491, pp. 640–649) https://doi.org/10.1016/j.apsusc.2019.06.108
  36. Romain AC, Nicolas J (2010) “Long term stability of metal oxide-based gas sensors for e-nose environmental applications: An overview” Sensors and Actuators B: Chemical (vol. 146, no. 2, pp. 502–506) https://doi.org/10.1016/j.snb.2009.12.027
  37. Romain A-C, André Ph, Nicolas J (2002) “Three years experiment with the same tin oxide sensor arrays for the identification of malodorous sources in the environment” Sensors and Actuators B: Chemical (vol. 84, no. 2, pp. 271–277) https://doi.org/10.1016/S0925-4005(02)00036-9
  38. Ionescu R, Vancu A, Tomescu A (2000) “Time-dependent humidity calibration for drift corrections in electronic noses equipped with SnO2 gas sensors” Sensors and Actuators B: Chemical (vol. 69, no. 3, pp. 283–286) https://doi.org/10.1016/S0925-4005(00)00508-6
  39. Wang G, Yang Y, Han D, Li Y (2017) “Oxygen defective metal oxides for energy conversion and storage” Nano Today (vol. 13, pp. 23–39) https://doi.org/10.1016/j.nantod.2017.02.009
  40. O’Regan B, Grätzel M (1991) “A low-cost, high-efficiency solar cell based on dye-sensitized colloidal TiO 2 films” Nature (vol. 353, no. 6346, pp. 737–740) https://doi.org/10.1038/353737a0
  41. Yang X, Wolcott A, Wang G, Sobo A, Fitzmorris RC, et al. (2009) “Nitrogen-doped ZnO nanowire arrays for photoelectrochemical water splitting” Nano Lett (vol. 9, no. 6, pp. 2331–2336) https://doi.org/10.1021/nl900772q
  42. Hoang S, Guo S, Hahn NT, Bard AJ, Mullins CB (2012) “Visible light driven photoelectrochemical water oxidation on nitrogen-modified TiO2 nanowires” Nano Lett (vol. 12, no. 1, pp. 26–32) https://doi.org/10.1021/nl2028188
  43. Kenney MJ, Gong M, Li Y, Wu JZ, Feng J, et al. (2013) “High-performance silicon photoanodes passivated with ultrathin nickel films for water oxidation” Science (vol. 342, no. 6160, pp. 836–840) https://doi.org/10.1126/science.1241327
  44. Wang G, Wang H, Ling Y, Tang Y, Yang X, et al. (2011) “Hydrogen-treated TiO2 nanowire arrays for photoelectrochemical water splitting” Nano Lett (vol. 11, no. 7, pp. 3026–3033) https://doi.org/10.1021/nl201766h
  45. Wang H, Qian F, Wang G, Jiao Y, He Z, et al. (2013) “Self-biased solar-microbial device for sustainable hydrogen generation” ACS Nano (vol. 7, no. 10, pp. 8728–8735) https://doi.org/10.1021/nn403082m
  46. Yang Y, Ling Y, Wang G, Liu T, Wang F, et al. (2015) “Photohole induced corrosion of titanium dioxide: Mechanism and solutions” Nano Lett (vol. 15, no. 10, pp. 7051–7057) https://doi.org/10.1021/acs.nanolett.5b03114
  47. Cheng L, Hou Y, Zhang B, Yang S, Guo JW, et al. (2013) “Hydrogen-treated commercial WO3 as an efficient electrocatalyst for triiodide reduction in dye-sensitized solar cells” Chem Commun (vol. 49, no. 53, pp. 5945–5947) https://doi.org/10.1039/C3CC42206B
  48. Lu X, Yu M, Wang G, Zhai T, Xie S, et al. (2013) “ H-TiO2@MnO2//H-TiO2@C core–shell nanowires for high prformance and flexible asymmetric supercapacitors” Advanced Materials (vol. 25, no. 2, pp. 267–272) https://doi.org/10.1002/adma.201203410
  49. Kang Q, Cao J, Zhang Y, Liu L, Xu H, et al. (2013) “Reduced TiO2 nanotube arrays for photoelectrochemical water splitting” J Mater Chem A (vol. 1, no. 18, pp. 5766–5774) https://doi.org/10.1039/C3TA10689F
  50. Liang Z, Zheng G, Li W, Seh ZW, Yao H, et al. (2014) “Sulfur cathodes with hydrogen reduced titanium dioxide inverse opal structure” ACS Nano (vol. 8, no. 5, pp. 5249–5256) https://doi.org/10.1021/nn501308m
  51. Tan H, Zhao Z, Niu M, Mao C, Cao D, et al. (2014) “A facile and versatile method for preparation of colored TiO2 with enhanced solar-driven photocatalytic activity” Nanoscale (vol. 6, no. 17, pp. 10216–10223) https://doi.org/10.1039/C4NR02677B
  52. Ma D, Shi J-W, Zou Y, Fan Z, Ji X, et al. (2017) “Highly efficient photocatalyst based on a CdS quantum Dots/ZnO nanosheets 0D/2D heterojunction for hydrogen evolution from water splitting” ACS Appl Mater Interfaces (vol. 9, no. 30, pp. 25377–25386) https://doi.org/10.1021/acsami.7b08407
  53. Lam DV, Won S, Shim HC, Kim J-H, Lee S-M (2019) “Turning cotton into tough energy textile via metal oxide assisted carbonization” Carbon (vol. 153, pp. 257–264) https://doi.org/10.1016/j.carbon.2019.07.010
  54. Younis SA, Kwon EE, Qasim M, Kim K-H, Kim T, et al. (2020) “Metal-organic framework as a photocatalyst: Progress in modulation strategies and environmental/energy applications” Progress in Energy and Combustion Science (vol. 81, pp. 100870) https://doi.org/10.1016/j.pecs.2020.100870
  55. Li R, Wu S, Wan X, Xu H, Xiong Y (2016) “Cu/TiO2 octahedral-shell photocatalysts derived from metal–organic framework@semiconductor hybrid structures” Inorg Chem Front (vol. 3, no. 1, pp. 104–110) https://doi.org/10.1039/C5QI00205B
  56. Kidanemariam A, Lee J, Park J (2019) “Recent innovation of metal-organic frameworks for carbon dioxide photocatalytic reduction” Polymers (vol. 11, no. 12, pp. 2090) https://doi.org/10.3390/polym11122090
  57. Senanayake SD, Ramírez PJ, Waluyo I, Kundu S, Mudiyanselage K, et al. (2016) “Hydrogenation of CO2 to methanol on CeOx/Cu(111) and ZnO/Cu(111) catalysts: Role of the metal–oxide interface and importance of Ce3+ site” J Phys Chem C (vol. 120, no. 3, pp. 1778–1784) https://doi.org/10.1021/acs.jpcc.5b12012
  58. Gao S, Lin Y, Jiao X, Sun Y, Luo Q, et al. (2016) “Partially oxidized atomic cobalt layers for carbon dioxide electroreduction to liquid fuel” Nature (vol. 529, no. 7584, pp. 68–71) https://doi.org/10.1038/nature16455
  59. Humayun M, Qu Y, Raziq F, Yan R, Li Z, et al. (2016) “Exceptional visible-light activities of TiO2-coupled N-doped porous perovskite LaFeO3 for 2,4-dichlorophenol decomposition and CO2 conversion” Environ Sci Technol (vol. 50, no. 24, pp. 13600–13610) https://doi.org/10.1021/acs.est.6b04958
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